Tris(methylcyclopentadienyl)yttrium(III)

Synonym: Y(MeCp)3, Tris[(1,2,3,4,5-H)-1-Methyl-2,4-Cyclopentadien-1-Yl]-

MFCD00145485 | 630-916-1

Tris(methylcyclopentadienyl)yttrium(III), also designated by product code Y5720 (CAS 329735-72-0), is a high-purity organometallic yttrium(III) complex supplied as yellow crystals with a 99.9%-Y metal purity.

Characterized by its excellent volatility, Y(MeCp)3 boasts the highest vapor pressure among surveyed yttrium precursors. This exceptional property is critical for achieving optimal growth rates in Metal-Organic Chemical Vapor Deposition (MOCVD) processes. Due to its extreme air and moisture sensitivity, this flammable, water-reactive solid must be handled strictly under an inert atmosphere.

In thin-film applications, this chemical serves as a premier precursor for the Atomic Layer Deposition (ALD) of yttria (Y2O3). It is also widely used to grow complex oxides like Yttria-Stabilized Zirconia (YSZ) when paired with a zirconium precursor, and YScO3 when combined with ScCp3. Notably, films deposited using Y(MeCp)3 exhibit significantly lower carbon and hydrogen impurity levels compared to alternative options, ensuring superior structural and electronic film quality.

*This product is intended strictly for research and development usage and is not listed in the TSCA registry.*

Tris(methylcyclopentadienyl)yttrium(III) Chemical Structure

Overview

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing Tris(methylcyclopentadienyl)yttrium(III) contact us at sales@ereztech.com

Product Code Y5720
Product Name Tris(methylcyclopentadienyl)yttrium(III)
CAS Number 329735-72-0
Molecular formula C18H21Y
Linear formula Y(C6H7)3
Molecular weight 326.27
Form solid
Melting point 122-123C
UOM KG
Sensitivity air, moisture

Test Specification

Assay (purity) 98%+
Purity method by titration
Metal purity 99.9%-Y
Appearance yellow crystals
Titration %Y=26.7-27.8
Titration notes complexometric

Applications

Y₂O₃ thin film deposition by ALD/CVD

Y(MeCp)₃ serves as a premier precursor for the Atomic Layer Deposition (ALD) and Chemical Vapor Deposition (CVD) of pure yttria (Y₂O₃) thin films.

YSZ (yttria-stabilized zirconia) — use with zirconium precursor

Widely used for growing complex YSZ layers when paired with a compatible zirconium precursor, ensuring reliable structural quality.

YScO₃ high-k dielectric — use with ScCp₃

Applied in semiconductor manufacturing research for high-k gate dielectrics, deposited in combination with ScCp₃ precursors.

MOCVD process development and validation

Y(MeCp)₃ has the highest vapor pressure of surveyed yttrium precursors — critical for optimizing MOCVD growth rates.

Safety Information

Signal word DANGER
Pictograms GHS02 FlammableGHS07 Harmful - Irritant
UN 3396
Transport description Organometallic substance, solid, water-reactive, flammable Tris(methylcyclopentadienyl)yttrium
Hazardous class 4.3(4.1)
Packing group II
In TSCA registry No (sold for research and development usage only)

Frequently Asked Questions

What is Tris(methylcyclopentadienyl)yttrium(III) used for?
Tris(methylcyclopentadienyl)yttrium(III), or Y(MeCp)₃ (Product Code: Y5720), is primarily used as a high-purity organometallic precursor in thin-film deposition technologies. It is widely utilized for the Atomic Layer Deposition (ALD) and Chemical Vapor Deposition (CVD/MOCVD) of pure yttria (Y₂O₃) films, as well as complex oxide systems like Yttria-Stabilized Zirconia (YSZ) and high-k dielectrics like YScO₃.
What are the advantages of Y(MeCp)₃ vs. other yttrium precursors?
Y(MeCp)₃ possesses the highest vapor pressure among surveyed yttrium precursors, which is critical for achieving high MOCVD growth rates and consistent mass transport. Additionally, thin films deposited using Y(MeCp)₃ exhibit significantly lower carbon (C) and hydrogen (H) impurity levels compared to alternative precursors, resulting in superior structural and electronic film quality.
How should Y(MeCp)₃ be stored and handled safely?
Due to its extreme sensitivity to air and moisture, Y(MeCp)₃ is classified as a hazardous, water-reactive, and flammable solid (UN 3396, Class 4.3/4.1). It must be stored and handled strictly under an inert atmosphere (such as high-purity nitrogen or argon), typically inside a glovebox, and sealed in airtight containers to prevent rapid degradation and hazardous reactions.
Can Y(MeCp)₃ be used if it has been exposed to air or moisture?
No. Upon exposure to air or moisture, the yellow crystals of Y(MeCp)₃ will rapidly react and decompose, turning into non-volatile hydroxides or oxides. This completely compromises the complex’s volatility and 98%+ purity, making it unusable for volatile ALD/CVD gas-phase delivery lines and potentially creating safety risks in the deposition tool.
What are the melting point and thermal properties of Y5720?
Y5720 has a clean melting point window of 122–123°C, which allows for stable liquid-phase or solid-phase sublimation depending on your bubbler/delivery system configuration. Its exceptional volatility makes it highly compatible with standard thermal ALD windows and advanced PEALD processes.

Literature & Technical References

Peer-reviewed research and academic citations validating the deposition performance, thermal stability, and methodologies of Tris(methylcyclopentadienyl)yttrium(III).

Päiväsaari et al.
"Rare Earth Oxide Thin Films." Topics in Applied Physics, 2007.

Myllymäki et al.
"Atomic Layer Deposition of High-k Dielectrics." J. Mater. Chem., 2006.

External Identifiers for Y(MeCp)3

Pubchem CID 22564671
SMILES CC1=[C-]CC=C1.CC1=[C-]CC=C1.CC1=[C-]CC=C1.[Y+3]
IUPAC Name 2-methylcyclopenta-1,3-diene; yttrium(3+)
InchI Identifier InChI=1S/3C6H7.Y/c3*1-6-4-2-3-5-6;/h3*2,4H,3H2,1H3;/q3*-1;+3
InchI Key OXKRLQPVIZJLDT-UHFFFAOYSA-N

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